ConstantID

Sackur-Tetrode constant (1 K, 100 kPa)

Physico-chemicalMeasured

S0/R = −1.151 707 534 96(47)

Value
−1.151 707 534 96
Standard uncertainty
4.7 × 10−10
Relative uncertainty
4.1 × 10−10 (408 parts per trillion)
Status
Measured
Symbol
S0/R
Source
CODATA 2022 via NIST · NIST entry

Use in a calculation

# Sackur-Tetrode constant (1 K, 100 kPa), CODATA 2022 (NIST)
sackur_tetrode_constant_1_k_100_kpa = -1.15170753496  # standard uncertainty 4.7e-10

# SciPy: scipy.constants.physical_constants['Sackur-Tetrode constant (1 K, 100 kPa)']

What it is

The constant term in the Sackur–Tetrode equation for the entropy of a monatomic ideal gas, evaluated for particles of mass 1 u at 1 K and 100 kPa. Real entropies follow by adding terms for the actual mass, temperature and pressure.

Equations

  • S0R=52+ln[(mukT12πℏ2)3/2kT1p0]definition

How the value changed, 1998–2022

Each point is one CODATA adjustment, plotted as its difference from the 2022 value; the bars show one standard uncertainty (an arrowhead means the bar runs off the chart).

Sackur-Tetrode constant (1 K, 100 kPa): CODATA values 1998–2022 relative to the 2022 value, in parts per million, with one-standard-uncertainty bars−4−20+2+4parts per million1998200220062010201420182022

Relative uncertainty

Sackur-Tetrode constant (1 K, 100 kPa): relative standard uncertainty in each CODATA adjustment, logarithmic scale10⁻¹⁰10⁻⁹10⁻⁸10⁻⁷10⁻⁶10⁻⁵1998200220062010201420182022
CODATAValue (uncertainty)Relative uncertaintyChange from previous
2022−1.151 707 534 96(47)4.1 × 10−10 +4.7 σ of 2018
2018−1.151 707 537 06(45)3.9 × 10−10 +0.6 σ of 2014
2014−1.151 7084(14)1.2 × 10−6 −0.3 σ of 2010
2010−1.151 7078(23)2.0 × 10−6 −0.7 σ of 2006
2006−1.151 7047(44)3.8 × 10−6 +0.0 σ of 2002
2002−1.151 7047(44)3.8 × 10−6 +0.0 σ of 1998
1998−1.151 7048(44)3.8 × 10−6

“Change from previous” is the shift in the value divided by the standard uncertainty of the previous adjustment. Earlier values are converted into the current unit where NIST changed it (for example J s to J Hz⁻¹).

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