ConstantID

Boltzmann constant

Physico-chemicalAdoptedSI defining constantExact

k = 1.380 649 × 10−23 J K−1

Value
1.380 649 × 10−23 J K−1
Standard uncertainty
exact
Relative uncertainty
exact
Status
Exact since the 2019 SI redefinition
Symbol
k
Source
CODATA 2022 via NIST · NIST entry

Use in a calculation

# Boltzmann constant, CODATA 2022 (NIST)
k_B = 1.380649e-23  # J K^-1, exact

# SciPy: scipy.constants.physical_constants['Boltzmann constant']

What it is

The bridge between temperature and energy. In a gas at temperature T, each molecule carries on average 3kT/2 of kinetic energy from its motion. Since 2019 the value is exact and defines the kelvin, so temperature is now measured as an energy scale rather than against the triple point of water.

This is one of the seven defining constants of the SI. Its value was measured until the CODATA 2017 special adjustment fixed it, and it has been exact since the new definitions took effect on 20 May 2019.

Equations

  • E¯=32kTmean kinetic energy of a gas molecule
  • S=klnWBoltzmann's entropy formula
  • pV=NkTideal gas law
  • R=NAkmolar gas constant

In other units

Boltzmann constant in eV/K and other units →

How the value changed, 1998–2022

Each point is one CODATA adjustment, plotted as its difference from the 2022 value; the bars show one standard uncertainty (an arrowhead means the bar runs off the chart). Diamonds mark adjustments in which the value was exact.

Boltzmann constant: CODATA values 1998–2022 relative to the 2022 value, in parts per billion, with one-standard-uncertainty bars−1500−1000−5000+500+1000+1500parts per billion1998200220062010201420182022

Relative uncertainty

Boltzmann constant: relative standard uncertainty in each CODATA adjustment, logarithmic scale10⁻⁷10⁻⁶10⁻⁵199820022006201020142018exact2022exact
CODATAValue (uncertainty)Relative uncertaintyChange from previous
20221.380 649 × 10−23exact exact
20181.380 649 × 10−23exact +0.6 σ of 2014
20141.380 648 52(79) × 10−235.7 × 10−7 −0.2 σ of 2010
20101.380 6488(13) × 10−239.4 × 10−7 −0.7 σ of 2006
20061.380 6504(24) × 10−231.7 × 10−6 +0.0 σ of 2002
20021.380 6504(24) × 10−231.7 × 10−6 +0.0 σ of 1998
19981.380 6503(24) × 10−231.7 × 10−6

“Change from previous” is the shift in the value divided by the standard uncertainty of the previous adjustment. Earlier values are converted into the current unit where NIST changed it (for example J s to J Hz⁻¹).

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