ConstantID

Rydberg constant

Atomic & nuclearMeasured

R∞ = 10 973 731.568 157(12) m−1

Value
10 973 731.568 157 m−1
Standard uncertainty
1.2 × 10−5 m−1
Relative uncertainty
1.1 × 10−12 (1.1 parts per trillion)
Status
Measured
Symbol
R∞
Source
CODATA 2022 via NIST · NIST entry

Use in a calculation

# Rydberg constant, CODATA 2022 (NIST)
R_inf = 1.0973731568157e7  # m^-1, standard uncertainty 1.2e-5

# SciPy: scipy.constants.physical_constants['Rydberg constant']

What it is

Sets the scale of the wavelengths of light emitted by hydrogen-like atoms, computed for an infinitely heavy nucleus. It is one of the most precisely known constants, determined mainly from laser spectroscopy of hydrogen and deuterium.

Equations

  • 1λ≈R∞(1n12−1n22)Rydberg formula (heavy-nucleus limit)
  • R∞=α2mec2hin terms of other constants

In other units

UnitValue
CGS (cm−1)109 737.315 682

Converted with ConstantID's unit table; digits are rounded to the precision of the value, and a long exact value is rounded only for display. The relative uncertainty is unchanged by conversion to an exactly defined unit.

How the value changed, 1998–2022

Each point is one CODATA adjustment, plotted as its difference from the 2022 value; the bars show one standard uncertainty (an arrowhead means the bar runs off the chart).

Rydberg constant: CODATA values 1998–2022 relative to the 2022 value, in parts per trillion, with one-standard-uncertainty bars−60−40−200+20+40+60parts per trillion1998200220062010201420182022

Relative uncertainty

Rydberg constant: relative standard uncertainty in each CODATA adjustment, logarithmic scale10⁻¹³10⁻¹²10⁻¹¹1998200220062010201420182022
CODATAValue (uncertainty)Relative uncertaintyChange from previous
202210 973 731.568 157(12)1.1 × 10−12 −0.1 σ of 2018
201810 973 731.568 160(21)1.9 × 10−12 −5.4 σ of 2014
201410 973 731.568 508(65)5.9 × 10−12 −0.6 σ of 2010
201010 973 731.568 539(55)5.0 × 10−12 +0.2 σ of 2006
200610 973 731.568 527(73)6.7 × 10−12 +0.0 σ of 2002
200210 973 731.568 525(73)6.7 × 10−12 −0.3 σ of 1998
199810 973 731.568 549(83)7.6 × 10−12

“Change from previous” is the shift in the value divided by the standard uncertainty of the previous adjustment. Earlier values are converted into the current unit where NIST changed it (for example J s to J Hz⁻¹).

Related constants